全文获取类型
收费全文 | 100132篇 |
免费 | 8514篇 |
国内免费 | 4263篇 |
专业分类
电工技术 | 4080篇 |
技术理论 | 8篇 |
综合类 | 8756篇 |
化学工业 | 20730篇 |
金属工艺 | 2132篇 |
机械仪表 | 2177篇 |
建筑科学 | 14661篇 |
矿业工程 | 5698篇 |
能源动力 | 6363篇 |
轻工业 | 6351篇 |
水利工程 | 18829篇 |
石油天然气 | 8098篇 |
武器工业 | 224篇 |
无线电 | 1376篇 |
一般工业技术 | 4876篇 |
冶金工业 | 4552篇 |
原子能技术 | 1761篇 |
自动化技术 | 2237篇 |
出版年
2024年 | 201篇 |
2023年 | 1132篇 |
2022年 | 2320篇 |
2021年 | 2865篇 |
2020年 | 2985篇 |
2019年 | 2475篇 |
2018年 | 2427篇 |
2017年 | 2907篇 |
2016年 | 3327篇 |
2015年 | 3249篇 |
2014年 | 6168篇 |
2013年 | 6255篇 |
2012年 | 7634篇 |
2011年 | 7547篇 |
2010年 | 5549篇 |
2009年 | 5848篇 |
2008年 | 4989篇 |
2007年 | 6790篇 |
2006年 | 6255篇 |
2005年 | 5658篇 |
2004年 | 4523篇 |
2003年 | 4109篇 |
2002年 | 3566篇 |
2001年 | 2907篇 |
2000年 | 2437篇 |
1999年 | 1878篇 |
1998年 | 1339篇 |
1997年 | 1119篇 |
1996年 | 826篇 |
1995年 | 769篇 |
1994年 | 591篇 |
1993年 | 441篇 |
1992年 | 374篇 |
1991年 | 277篇 |
1990年 | 204篇 |
1989年 | 219篇 |
1988年 | 129篇 |
1987年 | 139篇 |
1986年 | 102篇 |
1985年 | 104篇 |
1984年 | 98篇 |
1983年 | 61篇 |
1982年 | 28篇 |
1981年 | 12篇 |
1980年 | 18篇 |
1979年 | 21篇 |
1978年 | 4篇 |
1977年 | 8篇 |
1976年 | 5篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
22.
23.
《International Journal of Hydrogen Energy》2022,47(66):28475-28485
Constructing efficient and stable bifunctional electrocatalysts for overall water splitting remains a challenge because of the sluggish reaction kinetics. Herein, the core-shell hybrids composed of Co(PO3)2 nanorod core and NiFe alloy shell in situ grown on nickel foam (NiFe/Co(PO3)2@NF) are synthesized. Owing to the hierarchical palm-leaf-like structures and strong adhesion between NiFe alloys, Co(PO3)2 and substrates, the catalyst provides a large surface area and rapid charge transfer, which facilitates active sites exposure and conductivity enhancement. The interfacial effect in the NiFe/Co(PO3)2 core-shell structure modulates the electronic structure of the active sites around the boundary, thereby boosting the intrinsic activity. Benefiting from the stable structure, the durability of the catalyst is not impaired by the inevitable surface reconfiguration. The NiFe/Co(PO3)2@NF electrode presents a low cell voltage of 1.63 V to achieve 10 mA cm?2 and manifests durability for up to 36 h at different current densities. 相似文献
24.
The slight-alkalization of generator internal cooling water (GICW) is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator. CO2 inleakage is increasingly identified as a potential security risk for GICW system. In this paper, the influence of CO2 inleakage on the slight-alkalization of GICW was theoretically discussed. Based on the equilibriums of the CO2-NaOH-H2O system, CO2 inleakage saturation was derived to quantify the amount of the dissolved CO2 in GICW. This parameter can be directly calculated with the measured conductivity and the [Na+] of GICW. The influence of CO2 inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed. The more severe the inleakage, the narrower the water quality operation ranges of GICW, resulting in the more difficult the slight-alkalization conditioning of GICW. The temperature calibrations of the conductivity and the pH value of GICW show non-linear correlations with the amount of CO2 inleakage and the NaOH dosage. This study provides insights into the influence of CO2 inleakage on the slight-alkalization of GICW, which can serve as the theoretical basis for the actual slight-alkalization when CO2 inleakage occurs. 相似文献
25.
Valentin Jolivet Yann Morizet Jonathan Hamon Michael Paris Tomo Suzuki-Muresan 《Journal of the American Ceramic Society》2021,104(3):1360-1369
The glass transition temperature (Tg) is a key parameter to investigate for application in nuclear waste immobilization in borosilicate glasses. Tg for several glasses containing iodine (I) has been measured in order to determine the I effect on Tg. Two series of glass composition (ISG and NH) containing up to 2.5 mol% I and synthesized under high pressure (0.5 to 1.5 GPa) have been investigated using differential scanning calorimetry (DSC). The I local environment in glasses has been determined using X-ray photoelectron spectroscopy and revealed that I is dissolved under its iodide form (I−). Results show that Tg is decreased with the I addition in the glass in agreement with previous results. We also observed that this Tg decrease is a strong function of glass composition. For NH, 2.5 mol% I induces a decrease of 24°C in Tg, whereas for ISG, 1.2 mol% decreases the Tg by 64°C. We interpret this difference as the result of the I dissolution mechanism and its effect on the polymerization of the boron network. The I dissolution in ISG is accompanied by a depolymerization of the boron network, whereas it is the opposite in NH. Although ISG corresponds to a standardized glass, for the particular case of I immobilization it appears less adequate than NH considering that the decrease in Tg for NH is small in comparison to ISG. 相似文献
26.
《International Journal of Hydrogen Energy》2022,47(49):21033-21043
Magnetron sputtered low-loading iridium-ruthenium thin films are investigated as catalysts for the Oxygen Evolution Reaction at the anode of the Proton Exchange Membrane Water Electrolyzer. Electrochemical performance of 50 nm thin catalysts (Ir pure, Ir–Ru 1:1, Ir–Ru 1:3, Ru pure) is tested in a Rotating Disk Electrode. Corresponding Tafel slopes are measured before and after the CV-based procedure to compare the activity and stability of prepared compounds. Calculated activities prior to the procedure confirm higher activity of ruthenium-containing catalysts (Ru pure > Ir–Ru 1:3 > Ir–Ru 1:1 > Ir pure). However, after the procedure a higher activity and less degradation of Ir–Ru 1:3 is observed, compared to Ir–Ru 1:1, i.e. the sample with a higher amount of unstable ruthenium performs better. This contradicts the expected behavior of the catalyst. The comprehensive chemical and structural analysis unravels that the stability of Ir–Ru 1:3 sample is connected to RuO2 chemical state and hcp structure. Obtained results are confirmed by measuring current densities in a single cell. 相似文献
27.
针对高河矿奥灰水文观测孔空水管锈蚀断裂漏水严重的问题,分析了存在的问题,制定了钻孔涌水封堵技术方案及相应的注浆施工工艺,并进行了为期7天的井下试验。封堵注浆压力达到6 MPa,使用注浆水泥50 t,水泥浆液凝固良好,注浆阀门打开后无出水现象。 相似文献
28.
尕斯库勒油田E13油藏已经进入高含水时期,储采失衡加剧,综合含水率达到了80%以上,原油产量下降,经济效益变差。为了提高油藏原油采出程度、改善油藏开发效果,调研了国内外减氧空气驱的机理研究以及现场试验的资料,建立了以油藏真实孔渗饱数据为基础的一维条形地层机理模型,并选取该油藏Y12-27井组进行了减氧空气驱可行性验证。研究表明:纵向顶部减氧空气驱驱油效果优于水驱和氮气驱;驱替压力对原油采出程度影响不大;注水转注气可以提高原油采出程度;对于减氧空气驱,由于低温氧化反应的作用,氧气浓度对原油采出程度有一定影响,但比较微弱,其中,氧气浓度为10%时,驱替结束采出程度最高;尕斯库勒油田E13油藏属于注水开发“双高”油藏,适用于减氧空气驱;对于该油藏Y12-27井组,顶部减氧空气驱驱油效果好于水驱和氮气驱,建议氧气浓度超过10%时采取关井等措施。 相似文献
29.
Bianka Rocha Saraiva Lucas Henrique Maldonado da Silva Fernando Antônio Anjo Ana Carolina Pelaes Vital Jéssica Bassi Da Silva Marcos Luciano Bruschi Paula Toshimi Matumoto Pintro 《International Journal of Food Science & Technology》2020,55(5):1962-1970
Debittered trub (brewing waste) is an important source of protein source (70.26%). Trub and whey protein were used for 5% protein enrichment of ice cream frozen by liquid nitrogen. Three formulations were elaborated: ice cream standard (ICS), ice cream with whey protein (ICW) and ice cream with trub (ICT). Chemical composition, rheological properties, texture, overrun, melting rate, scanning electron microscopy and a sensorial test were performed. Results showed that ICT presented a higher viscosity, obtained on the upward curve up to 6.76 Pa s−1, consistency index (22.96 (Pa s−1)n), hysteresis area (140.40 mPa s−1) and hardness (31113.33 g) but a lower melting rate (0.38 g min−1), overrun (13.92%) and sensorial acceptability than the other formulations. The addition of trub debittered for protein enrichment improved ice cream properties and demonstrated that it could be used as a food ingredient. 相似文献
30.
以Fe-Zn基废脱硫剂、煤、Na 2CO 3为原料进行高温炭热还原反应,制备了铁碳材料,实现了Zn和S的分离,有望能实现废脱硫剂的综合利用。考察不同工艺条件(配比,温度,时间)对铁碳材料品质,Zn单质分离效率和Na 2S的收率影响。结果表明: 反应温度≥900℃,煤∶废脱硫剂≥1,Na 2CO 3∶废脱硫剂≥1.5,反应时长≥2 h,Zn、S的分离回收效率可达到95%以上。且900℃制备的铁碳材料比表面高达193.6 m 2/g,介孔孔体积为0.028 cm 3/g,炭均匀附着于铁骨架。微电解-芬顿联用降解有机废水实验表明:仅微电解或微电解-芬顿联用(H 2O 2=COD=1500 mg/L)时,自制铁碳材料的稳定化学需氧量(COD)去除效率(41.78%、73.56%)都高于商业铁碳(8.43%、48.43%)。本文实验结果表明废脱硫剂与煤和碳酸钠混烧可实现废脱硫剂中Zn与S的分离回收,成功获得了比表面高、去除COD性能好的铁碳材料。 相似文献